|
Natural Gas
|
|
% of DFG
(Volume) |
SCF per
106 Btu
|
Lbs. per
106 Btu |
PPM |
Comments
|
| CO2 |
10.12
|
1033.0
|
119.76
|
|
Orsat & Calculation
|
| O2 |
3.00
|
306.0
|
25.80
|
|
Orsat & Calculation
|
| CO |
NIL
|
0.5
|
0.04
|
50
|
Colorimetric |
| N2 |
86.88
|
8873.0
|
654.80
|
|
Orsat & Calculation
|
| H2O |
|
2237.0
|
106.16
|
|
Calculations |
| TOTAL |
100.00
|
12449.5
|
906.56
|
|
|
| Particulates |
|
|
0.001
|
|
EPA Method 5 |
| NOX |
0.0085
|
|
0.12
|
100
|
Chemiluminescent |
| Hydrocarbons |
0.001
|
0.1
|
0.004
|
10
|
Flame Ionization |
| SOX |
NOT
APPLICABLE TO GAS |
|
|
Note:
Emissions corrected to 3% O2. |
|
CONDITIONS
|
| H2
|
22.31%
(Wt.) |
| C |
68.98%
(Wt.) |
| S |
0.00%
(Wt.) |
| HHV |
1,000
Btu/ft.3 |
| Sp. Gr.
|
0.619
|
Propane
|
|
% of DFG
(Volume) |
SCF per
106 Btu
|
Lbs. per
106 Btu |
PPM |
Comments
|
| CO2 |
11.43
|
1190.60
|
138.00
|
|
Orsat & Calculation
|
| O2 |
3.42
|
356.00
|
30.01
|
|
Orsat & Calculation
|
| CO |
NIL
|
0.20
|
0.07
|
50
|
Colorimetric |
| N2 |
85.15
|
8868.70
|
654.17
|
|
Orsat & Calculation
|
| H2O |
|
1523.70
|
72.25
|
|
Calculations |
| TOTAL |
100.00
|
11939.20
|
894.50
|
|
|
| Particulates |
|
|
0.001
|
|
EPA Method 5 |
| NOX |
|
|
0.15
|
120
|
Chemiluminescent |
| Hydrocarbon |
0.001
|
0.10
|
0.008
|
10
|
Flame Ionization |
| SOX |
NOT
APPLICABLE TO GAS |
|
|
Note:
Emissions corrected to 3% O2. |
|
CONDITIONS
|
| H2
|
18.29%
(Wt.) |
| C |
81.71%
(Wt.) |
| S |
0.00%
(Wt.) |
| HHV |
2,500
Btu/ft.3 |
| Sp. Gr.
|
0.619 |
No. 2, 4, 5, and Heavy Oil
|
|
% of DFG
(Volume) |
SCF per
106 Btu
|
Lbs. per
106 Btu |
PPM |
Comments
|
| CO2 |
13.78
|
1493.95
|
173.21
|
|
Orsat & Calculation
|
| O2 |
2.88
|
311.77
|
26.27
|
|
Orsat & Calculation
|
| CO |
NIL
|
0.55
|
0.04
|
100
|
Colorimetric |
| N2 |
83.34
|
9035.73
|
666.83
|
|
Orsat & Calculation
|
| H2O |
|
1365.57
|
64.81
|
|
Calculations |
| TOTAL |
100.00
|
12207.57
|
931.16
|
|
|
| Particulates |
|
EPA Method 5 |
| NOX |
|
Chemiluminescent |
| Hydrocarbon |
0.001
|
0.2
|
0.01
|
20
|
Flame Ionization |
| SOX |
|
|
|
|
Note:
Emissions corrected to 3% O2. |
|
CONDITIONS
|
| H2
|
10.9%
(Wt.) |
| C
|
86.6%
(Wt.) |
| S
|
2.0% (Wt.)
|
| HHV
|
18,330
Btu/lb |
| Sp. Gr.
|
0.986
|
SO2 Emission
|
Weight %
Sulfur
|
SO2Lb./MMBtu
|
PPM*
|
| 0 |
0 |
0 |
| 0.2
|
0.208
|
112
|
| 0.4
|
0.417
|
225
|
| 0.6
|
0.625
|
337
|
| 0.8
|
0.833
|
449
|
| 1.0
|
1.042
|
561
|
| 1.2
|
1.250
|
673
|
| 1.4
|
1.458
|
786
|
| 1.6
|
1.670
|
898
|
| 1.8
|
1.875
|
1010
|
| 2.0
|
2.083
|
1122
|
|
|
*Based
on 3% flue gas O2. |
NOx
Emission Data vs. Fuel - Bound Nitrogen
At 15% Excess Air and with Standard Burner
|
Weight
% Fuel-Bound
Nitrogen
|
Lbs./MMBtu
|
PPM
|
| 0.00
|
0.127
|
95
|
| 0.02
|
0.176
|
132
|
| 0.04
|
0.204
|
153
|
| 0.06
|
0.227
|
170
|
| 0.08
|
0.248
|
186
|
| 0.10
|
0.267
|
200
|
| 0.12
|
0.284
|
213
|
| 0.14
|
0.301
|
226
|
| 0.16
|
0.316
|
237
|
| 0.18
|
0.332
|
249
|
| 0.20
|
0.347
|
260
|
| 0.22
|
0.360
|
270
|
| 0.24
|
0.373
|
280
|
| 0.26
|
0.387
|
290
|
| 0.28
|
0.400
|
300
|
| 0.30
|
0.412
|
309
|
| 0.32
|
0.424
|
318
|
| 0.34
|
0.436
|
327
|
| 0.36
|
0.448
|
336
|
| 0.38
|
0.460
|
345
|
| 0.40
|
0.471
|
353
|
| 0.42
|
0.483
|
362
|
| 0.44
|
0.493
|
370
|
| 0.46
|
0.504
|
378
|
| 0.48
|
0.515
|
386
|
| 0.50
|
0.525
|
394
|
I.
Stack Emissions (Particulates) ES
vs. Sulfur content of Fuel
| % S
(wt) |
Es
Lbs./MMBtu |
| 0.0
|
0.0080
|
| 0.2
|
0.0092
|
| 0.4
|
0.0109
|
| 0.6
|
0.0132
|
| 0.8
|
0.0163
|
| 1.0
|
0.0203
|
| 1.2
|
0.0259
|
| 1.4
|
0.0335
|
| 1.6
|
0.0436
|
| 1.8
|
0.0573
|
| 2.0
|
0.0758
|
| 2.2
|
0.1000
|
| 2.4
|
0.1100
|
| 2.6
|
0.1210
|
| 2.8
|
0.1320
|
| 3.0
|
0.1400
|
II.
Particulate Emissions EG
vs. Conradson Carbon Residue content of Fuel
| % C.
C. R. |
Ec
Lbs./MMBtu |
| 0 -
9.0 |
0.0000
|
| 10.0
|
0.0007
|
| 11.0
|
0.0122
|
| 12.0
|
0.0238
|
| 13.0
|
0.0353
|
| 14.0
|
0.0469
|
| 15.0
|
0.0584
|
| 16.0
|
0.0700
|
| 17.0
|
0.0815
|
| 18.0
|
0.0931
|
| 19.0
|
0.1046
|
| 20.0
|
0.1162
|
| 21.0
|
0.1277
|
| 22.0
|
0.1392
|
| 23.0
|
0.1507
|
| 24.0
|
0.1622
|
III. Particulate
Emission EA
vs. Ash content of Fuel
| % Ash
|
EA
Lbs./MMBtu |
| 0.000
|
0.0000
|
| 0.020
|
0.0111
|
| 0.040
|
0.0222
|
| 0.060
|
0.0333
|
| 0.080
|
0.0444
|
| 0.100
|
0.0555
|
| 0.120
|
0.0667
|
| 0.140
|
0.0778
|
| 0.160
|
0.0889
|
| 0.180
|
0.1000
|
| 0.200
|
0.1111
|
| 0.220
|
0.1222
|
| 0.240
|
0.1333
|
| 0.260
|
0.1444
|
| 0.280
|
0.1555
|
| 0.300
|
0.1667
|
To find the
Total Particulate Emissions estimate, use the following formula:
ET
= ES - EG - EA
Molecular
Weights Used
| CO
|
=
|
28
|
N2
|
=
|
28
|
| CO2
|
=
|
44
|
NOX
|
=
|
46
for NO2 |
| H20
|
=
|
18
|
SOX
|
=
|
64
for SO2 |
| O2
|
=
|
32
|
CH4
|
=
|
16
|
|
Conversion
Data
| 1
PPM = 1 Part Per Million = 0.0001% |
| SCF
= Standard Cubic Feet at 60 deg. F at 14.7 psia |
| 1
pound - Mole = 380 SCF |
|
